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When an object is irradiated with X-rays of a certain energy or greater, the inner shell electrons of the atoms in the material are excited. When the outer shell electrons move to the holes that occur as a result of this, X-rays equal to the difference in energy between the inner and outer shells are released. This is called X-ray fluorescence.
The difference in energy between the inner and outer shells is unique for each element. Therefore, the energy of X-ray fluorescence is unique for each element. In addition, the energy is greater for shells that are closer to the nucleus. So, K shell > L shell > M shell. X-ray fluorescence that is emitted during a transition from the L shell to the K shell are called Kα rays, and the X-ray fluorescence that is emitted during a transition from the M shell to the K shell are called Kβ rays.
Since the energy of X-ray fluorescence is unique for each element, we can examine the fluorescence spectrum of a sample to analyze its constituent elements. (Figure 2) Also, by measuring the intensity of the spectrum, we can also determine the concentration of specific elements in a sample.
X-ray fluorescence analyzers can be broadly divided into two categories. One type are wavelength dispersive X-ray fluorescence analyzers (WDX) , which prepare X-ray fluorescence with Soller slits (extracting nearly parallel fluorescence emissions) and use spectroscopic crystals to take spectroscopic measurements. They have high detection sensitivity and high energy resolution, which makes them suitable for cases where a greater level of detection accuracy is required. The other type are energy dispersive X-ray fluorescence analyzers (EDX), which are usually equipped with a semiconductor detector. Since the semiconductor detector itself has a function to analyze energy, the features of this type include compact size, short analysis time, and simultaneous multi-element analysis.
Quantitative analysis is a method of determining the content of elements in a sample. For X-ray fluorescence analysis, this method is broadly divided into two categories: the calibration curve method and the fundamental parameter (FP) method.
Although X-ray fluorescence analysis allows a variety of samples, such as solids, liquids, and powders, to be analyzed non-destructively, there is a possibility that the analysis results may differ depending on the shape of the sample or how the sample is placed in the container. (Figure 3) Therefore, the following points are important when preparing samples.
Figure 3 Effects of specimen surface and granularity (particle size)
Attention is paid to measures against hazardous chemical substances as an environmental issue. RoHS directives and other regulations are emerging in order to prevent the diffusion of hazardous chemical substances. With such trends, X-ray fluorescence analyzers (XRF) that can perform screening analyses quickly and easily are required.
* Revisions may be made to the legal interpretations of these regulations. The statements here do not represent the positions of official institutions. Be sure to refer to the original text of applicable laws and regulations.
The RoHS (Restriction of Hazardous Substances) was issued by the EU in 2003, and came into force in July 2006.
Therefore, in order to ship products to EU member countries, the content of six types of hazardous substances specified in RoHS must be less than the specified values. (Table 1) X-ray fluorescence analyzers (XRF) are non-destructive and can perform measurements very quickly, which makes them useful for screening hazardous substances. In addition, XRF can be used to perform both qualitative and quantitative analyses. Hexavalent chromium is detected as total chromium, and PBB/PBDE are analyzed as total bromine.
|Lead (Pb)||1000ppm less|
|Mercury (Hg)||1000ppm less|
|Cadmium (Cd)||100ppm less|
|Hexavalent chromium (Cr6+)||1000ppm less|
|Polybrominated biphenyl (PBB)||1000ppm less|
|Polybrominated biphenyl tail (PBDE)||1000ppm less|
The Soil Contamination Countermeasures Act came into effect in February 2003 in order to prevent damage to health due to soil contamination and to gain a better understanding of contamination conditions. Among the specific hazardous substances that are specified in this law, the components of Class 2 heavy metals can be analyzed with X-ray fluorescence.
The specified substances and their reference values are shown in Table 2. An official quantification method is enacted only for total arsenic and total lead (JIS K 0470).
|Hexavalent chromium (Cr6+)||250mg/kg|
Toy safety is regulated by Part 3 of the EU Toy Safety Directive (EN71 Part 3).
It stipulates regulations regarding the oral intake of heavy metals in toys that are designed for children aged 6 or younger, and that could be placed in the mouth or swallowed. The target metal elements and their regulation values are shown in Table 3.
In Japan, Toy Safety Standards (ST-2002) have been established, and the regulation value for lead (90 ppm) was added in May 2006.
These ST standards include the Food Sanitation Act, EN71, and other regulations as inspection items.
|Excluding clay and
|Clay and finger point|
|Hexavalent chromium (Cr6+)||60ppm||25ppm|
Halogen compounds have been used widely in electronic materials and other products as fire retardant materials. However, because they generate harmful gas when burned (dioxin in particular can be produced at high temperature) and for environmental concerns such as preventing the destruction of the ozone layer, there is now a strong need to switch to halogen-free materials. However, there is no clear definition of "halogen-free".
For example, the Japan Electronics Packaging and Circuits Association (JPCA) has established regulation values for halogen content in printed wiring as a JPCA standard (Test Method for Halogen-Free Materials JPCA-ES01). It defines the total amount of chlorine (Cl) and bromine (Br) contained in epoxy resin and phenolic resin used in printed wiring boards. (Table 4)
This standard has also been adopted for IEC standard 61249-2-21 (International Electrotechnical Commission) and IPC standard 4101B (Association Connecting Electronics Industries).
table4 Total amount of chlorine and bromine in the JPCA standard
|Chlorine (Cl)||Total amount of 900ppm or less|